Delayed Die Swell and Sedimentation of Elongated Particles in Wormlike Micellar Solutions

نویسندگان

  • M. CLOITRE
  • T. HALL
  • C. MATA
چکیده

It has been recently proposed that the combined action of inertia and non-linear viscoelasticity may be the origin of very peculiar behaviors with dramatic changes of flow type. Two examples are the problem of delayed die swell and the orientation of elongated particles sedimenting in solutions of wormlike micelles. These solutions give rise to well defined viscoelastic properties which can be tuned precisely by changing the surfactant weight fraction. Our analysis does not rely on any constitutive equation and our results strongly support the interpretation that delayed die swell and sedimetation of long bodies in wormlike micellar solutions are ruled by a change of flow type from subcritical to supercritical.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Strip waves in vibrated shear-thickening wormlike micellar solutions.

We present an instability in vertically vibrated dilute wormlike micellar solutions. Above a critical driving acceleration the fluid forms elongated solitary domains of high amplitude waves. We model this instability using a Mathieu equation modified to account for the non-Newtonian character of the fluid. We find that our model successfully reproduces the observed transitions.

متن کامل

Microrheology of wormlike micellar fluids from the diffusion of colloidal probes.

The microrheology of cationic micellar solutions has been investigated as a function of added organic salts using quasielastic light scattering (QELS). Two organic salts, sodium p-toluene sulfonate and sodium salicylate, were used to induce microstructural changes in cetyl trimethylammonium bromide (CTAB) micelles. The mean-squared displacement (MSD) of polystyrene probe particles embedded in C...

متن کامل

Influence of nanoparticle addition on the properties of wormlike micellar solutions.

The addition of positively charged, 30 nm diameter silica nanoparticles to cationic wormlike micellar solutions of cetyltrimethylammonium bromide and sodium nitrate is studied using a combination of rheology, small angle neutron scattering, dynamic light scattering, and cryo-transmission electron microscopy. The mixtures are single phase up to particle volume fractions of 1%. The addition of li...

متن کامل

Paula Vasquez

Wormlike micellar solutions are composed of long flexible structures that result from self-assembly processes of surfactant molecules. At high enough concentration, these wormlike micelles can entangle and give viscoelastic properties to the solution just like typical polymers. Micellar solutions, in contrast to polymeric solutions, have two different relaxation mechanisms. One is the reptation...

متن کامل

Effect of Counterion Structure on Micellar Growth of Alkylpyridinium Surfactants in Aqueous Solution.

This paper describes the influence of counterions on the unidirectional growth of micelles formed by alkylpyridinium surfactants in aqueous solution. It is shown that the growth of spherical micelles to form wormlike micelles is strongly dependent on counterion structure. More hydrophobic counterions induce the formation of wormlike micelles at lower surfactant concentrations. Next to hydrophob...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 1998